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    • #101 (LOMC)
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#103 Laboratory for Stereochemistry of Organometallic Compounds (LSOC)

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Head of the laboratory: Professor, Dr.Sc., Viacheslav I. Sokolov

(tel. +7-499-135-92-11; e-mail )

 

Other employees:

Abramova N.V., Bulygina L.A., Ginzburg A.G., Khruscheva N.S., Kuznetsov N.Yu., Kamishova A.A., Polukeev A,V., Safronov S.V.

 

Main publications in 2010-2011:

1. V.I. Sokolov, E.G. Rakov, N.A.Bumagin, M.G.Vinogradov.  Fullerenes, Nanotubes, and Carbon Nanostructures, 18: 558–563 (2010). New Method to Prepare Nanopalladium Clusters Immobilized on Carbon Nanotubes: A Very Efficient Catalyst for Forming Carbon-Carbon Bonds and Hydrogenation.

2. O.V. Turova, E.V. Starodubtseva, M.G. Vinogradov, V.I. Sokolov, N.V. Abramova, A.Y. Vul’,  A.E. Alexenskiy. Catal. Commun., accepted (2010). Palladium supported on detonation nanodiamond as a highly effective catalyst of the C=C and CºC bonds hydrogenation.

3. V.I. Sokolov, L.N.Nikitin, L.A.Bulygina, V.N.Khrustalev, Z.A.Starikova, A.R.Khokhlov. J. Organomet. Chem., 695, 799-803, №3 (2010). Supercritical carbon dioxide in organometallic synthesis. Combination of sc-CO2 with Nafion film as a novel reagent in the synthesis of ethers from hydroxymethylmetallocenes.

4. O.V. Turova, E.V. Starodubtseva, M.G. Vinogradov, V.I. Sokolov, N.V. Abramova, A.Y. Vul’,  A.E. Alexenskiy. Catal. Commun., 12, 577 (2011). Palladium supported on detonation nanodiamond as a highly effective catalyst of the C=C and CºC bonds hydrogenation.

5. A.G.Ginzburg, Bashilov V.V., Dolgushin F.M. Smolyakov A.F., Petrovskii P.V., Sokolov V.I. Inorg. Chim. Acta, 370, 292 (2011). Change of the coordination type for the phospholyl ligand under nucleophilic attack of H2O on phosphorus atom in 2,5-diphenylphosphacymantrene promoted by aliphatic amines.

6. M.V.Tsikalova, Zheludkov S.V. Vorontsov E.I., Bashilov V.V., Babievskii K.K., Sokolov V.I., Novikov Yu.N. Mendeleev Communications, 21, # 7, 256 (2011). Optically active rhodium and iridium C60 complexes containing the enantiomeric ligand (+)DIOP: (h2-C60)MH(CO)[(+)DIOP] (M=Rh, Ir).

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#103 (LSOC)