Other employees:
Lyudmila A. Chekulaeva, Sergey A. Glazun, Anna A. Ilinova, Irina D. Kosenko, Julia N. Laskova, Irina A. Lobanova, Lyudmila S. Podvysotskaya, Andrey A. Semioshkin, Akim V. Shmal’ko, Igor B. Sivaev, Marina Yu. Stognii, Sergey V. Timofeev, Olga B. Zhidkova, S.A. Anufriev, G.S. Kazakov
Research area:
Synthesis and study of reactivity of polyhedral boranes, carboranes, and metallacarboranes. Development of methods of introduction of functional groups to boron polyhedrons in order to prepare conjugates with different biomolecules (amino acids, nucleosides, carbohydrides, lipids, porphyrins, phthalocyanines). Search of application of compounds prepared in medicine for diagnostics of malignant tumours and for boron neutron capture therapy of cancer. Development of new methods for the synthesis of practically valuable metal-containing compounds used for molecular conductors, semiconductor and ceramic materials.
Publications 2009-2011:
1. I.B.Sivaev, V.I.Bregadze, Polyhedral Boranes for Medical Applications: Current Status and Perspectives, Eur. J. Inorg. Chem., 2009, 1433-1450.
2. A.Semioshkin, Ju.Laskova, B.Wojtczak, A.Andrysiak, I.Godovikov, V.Bregadze, Z.Lesnikowski, Synthesis of closo-dodecaborate based nucleoside conjugates, J. Organomet. Chem., 2009, 694, 1375-1379.
3. V.I.Bregadze, I.B.Sivaev, I.A.Lobanova, R.A.Titeev, D.I.Brittal, M.A.Grin, A.F.Mironov, Conjugates of boron clusters with derivatives of natural chlorin and bacteriochlorin, Appl. Radiat. Isotopes, 2009, 67, S101-S104.
4. V.I.Bregadze, A.A.Semioshkin, Ju.N.Laskova, M.Ya.Berzina, I.A.Lobanova, I.B.Sivaev, M.A.Grin, R.A.Titeev, D.I.Brittal, O.V.Ulybina, A.V.Chestnova, A.A.Ignatova. A.V.Feofanov, A.F.Mironov, Novel types of boronated chlorine e6 conjugates via “click chemistry”, Appl. Organometal. Chem., 2009, 23, 370-374.
5. N.P.Kushwah, V.K.Jain, A.Wadawale, O.B.Zhidkova, Z.A.Starikova, V.I.Bregadze, Synthesis, spectroscopy and structures of palladium(II) and platinum(II) complexes containing mercapto-o-carborane, J. Organomet. Chem., 2009, 694, 4146-4151.
6. A.A.Semioshkin, Ju.N.Laskova, O.B.Zhidkova, I.A.Godovikov, Z.A.Starikova, V.I.Bregadze, D.Gabel, Synthesis and Structure of Novel Closo-Dodecaborate Based Glycerols, J. Organomet. Chem., 2010, 695, 370-374.
7. V.Bregadze, I.Sivaev, I.Lobanova, O.Kazheva, G.Alexandrov, A.Kravchenko, V.Starodub, L.Buravov, L.Titov, O.A.Dyachenko. Synthesis, structure and electrical conductivity of fulvalenium salts of cobalt bis(dicarbollide) anion and its derivatives, J. Chem. Sci., 2010, 122, 37-41.
8. Y.Li, Q.Jiang, Y.Li, H.Yan, V.I.Bregadze, Cobalt-Mediated B−H Activation and Cyclopentadienyl-Participated Diels−Alder Addition in the Reaction of a 16e CpCo Complex Containing an o-Carborane-1,2-dithiolato Ligand with HC≡C−C(O)Ph, Inorg. Chem., 2010, 49, 4-6.
9. M.Yu.Stogniy, I.B.Sivaev, P.V.Petrovskii and V.I.Bregadze, Synthesis of monosubstituted functional derivatives of ortho-carborane on the base of 1-mercapto-ortho-carborane: 1-HOOC(CH2)nS-1,2-C2B10H11 and [7-HOOC(CH2)nS-7,8-C2B9H11]- (n = 1÷4), Dalton Trans., 2010, 39, 1817–1822.
10. V.I.Bregadze, I.D.Kosenko, I.A.Lobanova, Z.A.Starikova, I.A.Godovikov, I.B.Sivaev, C-H Bond Activation of Arenes by [8,8’-μ-I-3,3’-Co(1,2-C2B9H10)2] in the Presence of Sterically Hindered Lewis Bases, Organometallics, 2010, 29, 5366-5372.
11. A.Semioshkin, J.Laskova, A.Ilinova, V.Bregadze, Z.J.Lesnikowski, Reactions of oxonium derivatives of [B12H12]2- with sulphur nucleophiles. Synthesis of novel B12-based mercaptanes, sulfides and nucleosides, J. Organomet. Chem., 2011, 696, 539-543.
12. O.N.Kazheva, G.G.Alexandrov, A.V.Kravchenko, I.D.Kosenko, I.A.Lobanova, I.B.Sivaev, O.A.Filippov, E.S.Shubina, V.I.Bregadze, V.A.Starodub, L.V.Titov, L.I.Buravov, O.A.Dyachenko, Molecular Conductors with 8-Hydroxy Cobalt Bis(dicarbollide) Anion, Inorg. Chem., 2011, 50, 444-450.
13. M.A.Grin, R.A.Titeev, D.I.Brittal, O.V.Ulybina, A.G.Tsiprovskiy, M.Ya.Berzina, I.A.Lobanova, I.B.Sivaev, V.I.Bregadze, V.F.Mironov, New conjugates of cobalt bis(dicarbollide) with chlorophyll a derivatives, Mendeleev Commun., 2011, 21, 84-86.
14. A.V.Prikaznov, A.V.Shmal’ko, I.B.Sivaev, P.V.Petrovskii, V.I.Bragin, A.V.Kisin, V.I.Bregadze, Synthesis of Carboxylic Acids Based on the closo-Decaborate Anion, Polyhedron, 2011, 30, 1494-1501.
15. A.Semioshkin, V.Bregadze, I.Godovikov, A.Ilinova, J.Laskova, Z.Starikova, Synthesis and structure of 1-iodo-7-dioxonium-decahydro-closo-dodecaborate, J. Organomet. Chem., 2011, 696, 2760-2762.
16. V.Bregadze, A.Semioshkin, I.Sivaev, Synthesis of conjugates of polyhedral boron compounds with tumor-seeking molecules for neutron capture therapy, Appl. Radiat. Isotopes, 2011, 69, 1774-1777.
17. A.Semioshkin, V.Bregadze, I.Godovikov, A.Ilinova, Z.J.Lesnikowski, I.Lobanova, A convenient approach toward boron cluster modifications with adenosine and 2’-deoxyadenosine, J. Organomet. Chem., 2011, 696, 3750-3755.
18. M.Pal, V.K.Jain, A.Wadawale, S.Glazun, Z.A.Starikova, V.I.Bregadze, Synthesis and spectroscopy of cis-configured mononuclear palladium(II) and platinum(II) complexes of chalcogeno o-carboranes and structures of [Pt(SCboPh)2(dppm)], [Pt(SeCboPh)2(dppm)], [Pt(SCboS)(PMe2Ph)2] and [Pt(SCboS)(PMePh2)2], J. Organomet. Chem., 2011, 696, 4257-4263.
19. V.I.Bregadze, I.B.Sivaev, Polyhedral Boron Compounds for BNCT, in Boron Science: New Technologies and Applications, Ed. N.S.Hosmane, CRC Press, 2011, p. 181-207.
20. I.B.Sivaev, V.I.Bregadze, Cyclic Oxonium Derivatives as Efficient Synthetic Tool for Modification of Polyhedral Boron Hydrides, in Boron Science: New Technologies and Applications, Ed. N.S.Hosmane, CRC Press, 2011, p. 623-637.
