Aleksandr M. Kal'sin, Arkadii Z. Kreindlin, Vasilii V. Krivykh, Vera A. Koneva, Tatyana A. Peganova, Oleg V. Semeikin, Elena S. Taits, Kamil I. Utegenov, Dmitrii N. Zarubin, Anton A. Zhizhin, Pavel A. Zhizhko, Svetlana V. Osintseva, Nikolai A. Shteltser.
New selective reactions for formation and cleavage of carbon–carbon, carbon–hydrogen, and carbon–heteroatom bonds in carbene-, carbyne-, and heterocumulene transition metal complexes and their derivatives.
The development of homogeneous and heterogeneous catalysts for heterometathesis reactions of carbonyl –containing organic compounds and various heterocumulenes (N-sulfinylamines, sulfur diamines, isocyanates, etc.) from oxo- and imido complexes transition metals related to Group IV–VI. The development of the catalytic heterometathesis methodology.
Zwitter-ionic platinum group metal aminoiminophosphoranate complexes. Study of their structure features and the catalytic properties.
Current grants and contracts:
1. The project "Reactions of the manganese vinylidene and allenylidene complexes with phosphorus nucleophiles containing phosphorus-oxygen bonds" as a part of the Program of the Presidium of the Russian Academy of Sciences "Development of synthetic methods for new chemicals and new materials", Subprogram "Direct synthesis of substances with prescribed properties and formation of useful materials on their basis" (coordinator: Academician Bubnov Yu.N.).. Project leader: D.Sc., Professor N.A. Ustynyuk.
2. FP7-PEOPLE-IIF-2008 N 909423
The development of novel type chiral homogeneous catalysts formed as a result of self-organization of the achiral active site and the chiral inductor for asymmetric synthesis in aqueous solutions. Project leader: PhD, senior researcher A. M. Kalsin
3. Contract with OJSC "SIBUR Holding" (2010-2011)
Contract No. 8410 "Preparation of Styrene-Butadiene Rubber having functional groups in the chain by the radically initiated hydrothiolation reaction".
Contract No. 8411 "Preparation of Butadiene Rubber having functional groups in the chain by the carbo- and hydroalumination reactions".
Leader: PhD, senior researcher D.N. Zarubin.
Main publications in 2009-2011:
1. O.V. Gusev, T.A. Peganova, A.V. Gonchar, P.V. Petrovskii, K.A. Lyssenko, N.A. Ustynyuk. “Synthesis of diaminophosphonium salts [Ph2(ArNH)2P]+Br- (Ar = o-MeC6H4, p-MeC6H4, p-PriC6H4, p-EtO2CC6H4, p-MeOC6H4”. Phosphorus, Sulfur, Silicon, and the related elements 2009, 184, 322-331.
2. T.A. Peganova, A.V. Valyaeva, A.M. Kalsin, P.V. Petrovskii, A.O. Borissova, K.A. Lyssenko, N.A. Ustynyuk “Synthesis of aminoiminophosphoranate complexes of palladium and platinum and X-ray diffractional studies of the weak C-H…Pd interactions affecting the geometry of the PdNPN metallocycles”. Organometallics 2009, 28, 3021-3028.
3. A.A. Zhizhin, D.N. Zarubin, N.A. Ustynyuk, Molybdenum-mediated imido-transfer reaction of N-sulfynylamines with dimethylformamide, Mendeleev Commun., 2009, 19, 165-166
4. I.D. Grishin, V.V. Krivykh, A.A. Shchepalov, E.S. Taits, N.A. Ustynyuk, D.F. Grishin, Stable 17e manganese complexes in the synthesis of macromolecules. Izv. Akad. Nauk, Ser. Khim., 2009, 1808-1813; Russ. Chem. Bull., Int. Ed., 2009, 1866-1871.
5. V.V. Krivykh, I.V. Glukhov, Cationic η3-butadienyl complexes of chromium and manganese, Mendeleev Commun., 2010, 20, 177-179.
6. V.V. Krivykh, D.A. Valyaev, K.I. Utegenov, A.M. Mazhuga, E.S. Taits, O.V. Semeikin, P.V. Petrovskii, I.V. Glukhov, N.A. Ustynyuk, Protonation of Zwitter-Ionic Manganese and Rhenium Phosphoniostyryl Complexes (η5-C5H5)(CO)2M––C(+PR3)=C(H)Ph: Experimental and DFT Study, Eur. J. Inorg. Chem., 2011, (2), 201-211. http://dx.doi.org/10.1002/ejic.201000868
7. P.A. Zhizhko, A.A. Zhizhin, D.N. Zarubin,; N.A. Ustynyuk, D.A. Lemenovskii, B.N. Shelimov, L.M. Kustov, O.P. Tkachenko, G.A. Kirakosyan, Oxo/imido heterometathesis of N-sulfinylamines and carbonyl compounds catalyzed by silica-supported vanadium oxochloride. Journal of Catalysis, 2011, 283(1), 108-118.
8. E.S. Kotlova, M.V. Pavlovskaya, I.D. Grishin, O.V. Semeikin, N.A. Ustynyuk, D.F. Grishin, η5-cyclopentadienyl-η2-styrenedicarbonylmanganese for initiation of free-radical polymerization of vinyl monomers. Polymer Science, Series B, 2011, 53(3-4), 108-115.
9. D.A. Valyaev, N. Lugan, G. Lavigne, N.A. Ustynyuk, Synthesis of η1-α-Phosphinocarbene Complexes of Manganese and Mechanistic Insight into Their Base-Induced Transformations, Organometallics, 2011, 30(8), 2318-2332.
10. N. Lugan, I. Fernandez, D.A. Valyaev, R. Brousses, M.A. Sierra, N.A. Ustynyuk, Conformation of half-sandwich Mn(I) O-alkyl and O-aryl Fischer carbene complexes: a joined experimental-theoretical study. Acta Cryst. A67, 2011, C452