#102 Laboratory for Transition Metal pi-Complexes (LTMPC)

Head of the laboratory: Dr.Sc. Trifonov A.A.
(tel. +7-499-135-93-67; e-mail )

 

Other employees:

Е.V.Balagurova, М.М.Vinogradov, А.А.Kissel, D.А.Loginov, А.P.Molotkov, D.V.Muratov, А.I.Babkin, I.А.Gogolev, Е.А.Trifonova, N.V.Shvydkiy, L.S.Shul’pina, V.B.Kharitonov, А.V.Кolos, M.A.Arsenov, N.N.Efimov, Т.N.Petrushina, R.А.Pototskiy.

 

Research area:

The laboratory develops general approaches to the synthesis of mono- and polynuclear pi-complexes of d- and f-elements. The use of the synthesized complexes in homogeneous catalysis, as well as the products of catalytic reactions in photoelectronics and biochemistry, is also evaluated.

 

Main publications in 2018–2022:

1. I.V.Basalov, A.A.Kissel, A.A.Trifonov et al. «2-Imino-2,3-dihydrobenzoxazole—a useful platform for designing rare- and alkaline earth complexes with variable di- and trianionic O,N,N, ligands» Dalton Trans., 2022, 51, 1995-2004
2. V.A.Kirkina, A.A.Kissel, A.N.Selikhov et al. «Amine-boranes reactions promoted by lanthanide(II) ions» Chem. Commun., 2022, 58, 859-862
3. V.B.Kharitonov, D.V.Muratov, D.A.Loginov «Cyclopentadienyl complexes of group 9 metals in the total synthesis of natural products» Coord. Chem. Rev. 2022, 471, 214744
4. M.A.Arsenov, Y.V.Fedorov, D.V.Muratov et al. «Synthesis of isocoumarins and PAHs with electron-withdrawing substituents: impact of the substituent nature on the photophysical behavior» Dyes and Pigments. 2022, 206, 110653
5. G.B.Shul’pin, L.S.Shul’pina «Oxidation of Organic Compounds with Peroxides Catalyzed by Polynuclear Metal Compounds, A Review» Catalysts, 2021, 11, 186-223
6. Shvydkiy N., Petrushina T.N., Perekalin D.S. «Cyclobutadiene rhodium complexes as catalysts for the synthesis of amides from electron‐rich arenes, tosyl azide and co» ChemCatChem, 2021, 13, 2873-2878
7. K.Biriukov, M.M.Vinogradov, O.I.Afanasyev et al. «Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power» Catal. Sci. Technol., 2021, 11, 4922-4930
8. V.B.Kharitonov, S.A.Runikhina, Y.V.Nelyubina et al. «Easy access to versatile catalytic systems for C-H activation and reductive amination based on tetrahydrofluorenyl rhodium(III) complexes» Chem. Eur. J., 2021, 27, 10903-10912
9. A.N.Selikhov, E.N.Boronin, A.V.Cherkasov et al. «Tris(benzhydryl) and cationic bis(benzhydryl) Ln(III) complexes: Exceptional thermostability and catalytic activity in olefin hydroarylation and hydrobenzylation with substituted pyridines» Adv. Synth. Catal. 2020, 362, 5432-5443
10. A.P.Molotkov, M.A.Arsenov, D.A.Kapustin et al. «Effect of Cp-ligand methylation on Rh(III)-catalyzed annulations of aromatic carboxylic acids with alkynes: Synthesis of isocoumarins and PAHs for organic light-emitting devices» ChemPlusChem, 2020, 85, 334-345
11. M.M.Vinogradov, O.I.Afanasyev, Y.V.Nelyubina et al. «Osmium catalysis in the reductive amination using carbon monoxide as a reducing agent» Molecular catalysis, 2020, 498, 111260
12. N.V.Shvydkiy, E.A.Dlin, K.V.Ivanov et al. «Synthesis and reactivity of cyclobutadiene nickel bromide» Dalton Trans., 2020, 49, 6801-6806.
13. G.A.Gurina, A.A.Kissel, D.M.Lyubov et al. «Bis(alkyl) scandium and yttrium complexes coordinated by an amidopyridinate ligand: synthesis, characterization and catalytic performance in isoprene polymerization, hydroelementation and carbon dioxide hydrosilylation» Dalton Trans., 2020, 49, 638-650
14. V.B.Kharitonov, E.Podyacheva, Y.V.Nelyubina et al. «Fluorene complexes of group 9 metals: Fluorene effect and application for reductive amination» Organometallics, 2019, 38, 16, 3151–3158
15. D.A.Loginov, L.S.Shul’pina, D.V.Muratov, G.B.Shul’pin «Cyclopentadienyl cobalt(III) complexes: synthetic and catalytic chemistry» Coord. Chem. Rev., 2019, 387, 1–31.
16. N.V.Shvydkiy, O.Vyhivskyi, Y.Nelyubina, D.Perekalin «Design of manganese phenol pi-complexes as Shvo-type catalysts for transfer hydrogenation of ketones» ChemCatChem, 2019, 11, 1602-1605
17. V.B.Kharitonov, M.V.Makarova, M.A.Arsenov, et al. «Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination» Organometallics, 2018, 37, 2553–2562
18. E.A.Trifonova, N.M.Ankudinov, D.S.Perekalin «A Planar-Chiral Rhodium(III) Catalyst with a Sterically Demanding Cyclopentadienyl Ligand and Its Application in the Enantioselective Synthesis of Dihydroisoquinolones» Angew. Chem. Int. Ed. 2018, 57, 7714-7718
19. A.A.Kissel, A.A.Trifonov «N-Containing Ligands as Universal Coordination Environments for Rare-Earth Alkyl and Bis(alkyl) Complexes» INEOS OPEN, 2018, 1, 1-38
20. D.V.Vorobyeva, M.M.Vinogradov, Y.V.Nelyubina, et al. «Rhodium(III)-catalyzed CF₃-Carbenoid C-H Functionalization of 6-Arylpurines» Org. Biomol. Chem., 2018, 16, 2966-2974
21. D.A.Loginov, V.E.Konoplev «Oxidative coupling of benzoic acids with alkynes: catalyst design and selectivity» JOMC, 2018, 867, 14–24.