The laboratory was established in 1954. Professor Dmitry Nikolaevich Kursanov, being the corresponding member of the USSR Academy of Sciences was the founder of the laboratory.
Staff:
Babin V.N., Belousova T.A.,Borisov T.A., Zherebker K.Ya., Ikonnikov N.S., Kelbysheva E.S., Kiselev S.S., Kulikov N.N., Loim N.M., Lyakhovetsky Yu.I., Nikitin O.M., Orliva T.Yu., Osipova E.Yu., Pleshkova A.P., Rodionov A.N., Simenel A.A., Snegur L.V., Stepanov A.A., Telegina L.N., Tsidilin A.M., Cherstkov V.F.
Research area:
Synthesis and studies of the structure and reactivity of organometallic compounds under the conditions of ion and radical ion reactions in condensed and gas phases. The engineering aspect of these studies consists in the revelation of the practically important properties of the synthesized compounds (biological activity, catalytic, and photochromic properties, and others).
Recent main publications:
1. L.V. Snegur, Yu.S. Nekrasov, N.S. Sergeeva, Zh.V. Zhilina, V.V Gumenyuk, ZA. Starikova, A.A. Simenel, N.B. Morozova, I.K. Sviridova, and V.N. Babin. “Ferrocenylalkyl Azoles. Bioactivity, Synthesis, Structure”. Appl. Organomet. Chem. 2008, 22, 139-147.
2. Telegina L. N., Ezernitskaya M. G., Godovikov I. A., Babievskii K. K., Lokshin B. V., Strelkova T. V., Borisov Y. A., Loim N. M. Investigation of Photochemical Behaviour of Tricarbonyl Cyclopentadienylmanganese Derivatives with Carbamate Groups. Eur. J. Inorg. Chem. 2009, I. 24, p. 3636-36433.
3. Yury I., Lyakhovetsky, Vasily V. Bashilov, Tatyana V. Efanova, Elena A. Shilova, Viatcheslav I. Sokolov, Yuri S. Nekrasov, Roger Taylor. Trifluoromethylation of C60 and C70 with mercury(II) trifluoroacetate. Fullerenes, Nanotubes and Carbon Nanostructures, 17, 85-98, 2009.
4. Yu.S. Nekrasov, Yu.A. Borisov, R.S. Skazov, A.A. Simenel, L.V. Snegur, Yu.A. Belousov, A.N. Rodionov. The reactivity of ferrocenylalkyl azoles under the conditions of electrospray ionization. Journal of Organometallic Chemistry, Volume 694, Issue 12, 2009, P. 1807-1812.
5. Yury I. Lyakhovetsky, Elena A. Shilova, Vasily V. Bashilov, Viatcheslav I. Sokolov, Yuri S. Nekrasov, and Boris L. Tumanskii. Homolytic Reactive Mass spectrometry of Fullerenes: Interaction of C60 and C70 with Organo- and Organoelement Mercurials in the Electron Impact Ion Source of a Mass Spectrometer; EPR, CIDEP, and MS Studies of Several Analogous Reactions of C60 Performed in solution. J. Phys. Chem. A 2009, 113, 13700–13710.
6. A.A. Simenel, E.A. Morozova, L.V. Snegur, S.I. Zykova, V.V. Kachala, L.A. Ostrovskaya, N.V. Bluchterova, M.M. Fomina, Simple route to ferrocenylalkyl nucleobases. Antitumor activity in vivo, Appl. Organomet. Chem. 2009, 23, 219-224.
7. A.A. Simenel, G.A. Dokuchaeva, L.V. Snegur, A.N. Rodionov, M.M. Ilyin, S.I. Zykova, L.A. Ostrovskaya, N.V. Bluchterova, M.M. Fomina and V.A. Rikova, Ferrocene-modified thiopyrimidines: synthesis, enantiomeric resolution, antitumor activity, Appl. Organomet. Chem., 2011, 25, 70-75.
8. A.N. Rodionov, .A.A. Simenel, A.A. Korlyukov, V.V. Kachala, S.M. Peregudova, K.Ya. Zherebker, E.Yu. Osipova, Synthesis and properties of 5-ferrocenyl-1H-pyrazole-3-carbaldehydes, J. Organomet. Chem., 2011, 696, 2108-2115.
9. E.Yu. Osipova, A.N. Rodionov, A.A. Simenel, N.V. Konovalova, V.V. Kachala, Synthesis of Ferrocene-Modified Porphyrins by the Reductive Amination Reaction, Макрогетероциклы /Macroheterocycles/, 2011, 4(2) 124-126.
10. Yu. A. Kolbanovskii , Yu. A. Borisov, Ab initio МР2 study of reactions mechanism of С2 with halogens and hydrohalides. Mendeleev Communication, 2011,
11. S. E. Lyubimov, E. A. Rastorguev, P. V. Petrovskii, E. S. Kelbyscheva, N. M. Loim, V. A. Davankov, “Iridium-catalyzed asymmetric hydrogenation of imines in supercritical carbon dioxide using phosphite-type ligand”. Tetrahedron Letters, 2011, 52, 12, 1395-1397.
12. E. S. Kelbysheva, M. G. Ezernitskaya, T. V. Strelkova, Yu. A. Borisov, A. F. Smol’yakov, Z. A. Starikova, F. M. Dolgushin, A. N. Rodionov, B. V. Lokshin, and N. M. Loim «Photochemistry of - and n-donor bifunctional monosubstituted derivatives of cyclopentadienylmanganese tricarbonyl containing allyl group and photo- and thermoisomerization of corresponding dicarbonyl chelates» Organometallics, 2011, 30(16), 4342-4353.
13. Elena A. Shilova, Yury I. Lyakhovetsky, Alexander I. Belokon, Tatyana V. Ponomareva, Rashid G. Gasanov, Boris L. Tumanskii, and Yuri S. Nekrasov. Homolytic Reactive Mass Spectrometry of Fullerenes: Interaction of C60 and C70 with Ketones in the Electron Impact Ion Source of a Mass Spectrometer and the Comparison of Results with Those of Photochemical Reactions of C60 with Several Ketones in Solution. J. Am. Soc. Mass Spectrom. 2011, 22, 2021-2032.
14. Yu. S. Nekrasov, N. S. Ikonnikov, Yu. A. Belousov, and S. S. Kiselev. Comparative Studies of the Behavior of Neutral and Ionic Ferrocene Derivatives under Different Conditions of Electrospray Ionization. Journal of Analytical Chemistry, 2011, Vol. 66, No. 13, pp. 59–65.
15. R.A.Dvorikova,Yu.V.Korshak,L.N.Nikitin,M.I.Buzin,V.A.Shanditsev, Z.S.Klimenkova, A.L.Rusanov, A.R.Khokhlov, A.Lappas, A.Kostoupoulou. Ferrocene-containing polyphenylenes as precursors for magnetic nanomaterials. J.of characterization and developpement of novel materials, vol.2 ,№2,191-207 (2011).
