Staff:
Babahina G.M., Belkova N.V., Bilyachenko A.N., Golub I.E., Gutsul E.I., Dronova M.S., Kirkina V.A., Kozinets E.M., Krylova A.I., Levistkii M.M., Silantyev G.A., Titav A.A., Filippov O.A., Epshtein L.M., Yalymov A.I.
The main research lines are devoted to:
These studies are performed using combination of low temperature molecular spectroscopy measurements and quantum chemical calculations.
Current grants and contracts:
1. RFBR project N 10-03-00960-а (2010-2012) “Intermolecular interactions of polyfunctional boron hydrides with mono and polydentate XH acids”, project responsible E.S. Shubina
2. RFBR project N 08-03-00464-а (2008-2010) “Variety of the proton transfer pathways directed by non-classical hydrogen bonds with transition metal hydrides. Spectroscopic (IR, UV, NMR) and theoretical investigations ”, project responsible L.M. Epstein
3. RFBR project N 09-03-00869 (2009-2011) “ Supramolecular design based on macrocyclic pyrazolates of copper(I) and silver(I) ”, project responsible O.A. Fillipov
4. RFBR project N 08-03-92506-НЦНИЛ_а (2008-2011) “Experimental and theoretical investigation of intermolecular hydroamination of non-activated alkenes catalyzed by platinum and rhodium complexes ”, project responsible N.V. Belkova.
5. Program of the Division of Chemistry and Material Sciences of RAS “Theoretical and experimental investigation of chemical bond nature and mechanisms of chemical reactions and processes of major importance” (supervisor - academician O.M. Nefedov), sub-project “Intermolecular interactions and reaction mechanism for hydrogen ions migration and H2 transformation in coordination sphere of group 8, 10 transition metal complexes” (2010), project responsible E.S. Shubina
6. Russian Federation President grant (2010-2011) МК-314.2010.3 — project responsible O.A. Fillipov
7. Bilateral RAS-CNR program “Sustainable Catalytic Processes”, Russian coordinator — E.S. Shubina, Italian coordinator - M. Peruzzini, ICCOM CNR (2008-2010)
8. International research group “Homogeneous catalysis for sustainable development” involving partner laboratories from Russia, France and Italy, Coordinator - R. Poli, Russian coordinator — E.S. Shubina, (2008-2011) https://dri-dae.cnrs-dir.fr/IMG/pdf/catalyse_homogene_web.pdf
Most important publications in 2008-2010:
1. V. A. Levina, A. Rossin, N. V. Belkova, M. R. Chierotti, L. M. Epstein, O. A. Filippov, R. Gobetto, L. Gonsalvi, A. Lledós, E.S. Shubina, F. Zanobini, M. Peruzzini, “Acid-base interaction between transition metal hydrides results in dihydrogen bonding and assists H2 evolution”, Angew. Chem. Int. Ed. 2010, in press
2. N. V. Belkova, L. M. Epstein, E. S. Shubina, “Dihydrogen Bonding, Proton Transfer and Beyond: What We Can Learn from Kinetics and Thermodynamics” (Microreview) Eur. J. Inorg. Chem. 2010, 3555–3565.
3. P. A. Dub, N. V. Belkova, O. A. Filippov , J.-C. Daran, L. M. Epstein, A. Lledós, E. S. Shubina, R. Poli, “Solvent-Dependent Dihydrogen/Dihydride Stability for [Mo(CO)(Cp*)H2(PMe3)2]+[BF4]- Determined by Multiple SolventAnionCation Non-Covalent Interactions” Chem. Eur. J. 2010, 16, 189 — 201.
4. P. A. Dub, O. A. Filippov, N. V. Belkova, J.-C. Daran, L. M. Epstein, R. Poli, E. S. Shubina, “Hydrogen bonding to carbonyl hydride complex Cp*Mo(PMe3)2(CO)H and its role in proton transfer”, Dalton Trans., 2010, 39, 2008–2015.
5. P. A. Dub, O. A. Filippov, G.A. Silantyev, N. V. Belkova,. J.-C. Daran, L. M. Epstein, R. Poli, E. S. Shubina, “Protonation of Cp*M(dppe)H Hydrides: Peculiarities of the Osmium Congener” Eur. J. Inorg. Chem. 2010, 1489–1500.
6. V. A. Levina, O. A. Filippov, E. I. Gutsul, N. V. Belkova, L. M. Epstein, A. Lledós, E. S. Shubina, “Neutral Transition Metal Hydrides as Acids in Hydrogen Bonding and Proton Transfer: Media Polarity and Specific Solvation Effects” J. Am. Chem. Soc. 2010, 132, 11234–11246.
7. V. N. Tsupreva, O. A.Filippov, A. A. Titov, A. I.Krylova, I. B. Sivaev, V. I. Bregadze, L. Epstein, E. S. Shubina, “Interaction of Polyhedral Boron Hydride Anions [B10H10]2 and [B12H12]2- with Cyclic Copper and Silver 3,5-Bis(trifluoromethyl)pyrazolate Complexes”, J. Organomet. Chem. 2009, 1704-1707.
8. O. A. Filippov, V. N. Tsupreva, L. M. Golubinskaya, A. I. Krylova, V. I. Bregadze, A. Lledos, L. M. Epstein, E. S. Shubina Proton-Transfer and H2-Elimination Reactions of Trimethylamine Alane: Role of Dihydrogen Bonding and Lewis Acid-Base Interactions Inorg. Chem. 2009, 48, 3667-3678.
9. N. V. Belkova, M. Besora, M. Baya, P. A. Dub, L. M. Epstein, A. Lledós, R. Poli, P. O. Revin, E. S. Shubina, “Effect of the metal atom nature on hydrogen bonding and proton transfer to [Cp*MH3(dppe)]: tungsten vs. molybdenum” Chem. Eur. J. 2008, 14, 9921-9934.
10. O. A. Filippov, V. N. Tsupreva, L. M. Epstein, A. Lledos, E. S. Shubina, “Intermolecular HH Vibrations of Dihydrogen Bonded Complexes H3EH-···HOR in the Low-Frequency Region: Theory and IR Spectra, J. Phys. Chem. A 2008, 112, 8198–8204.
