RAS FASO RFBR RSF
  • Русский
INEOS Logo A. N. Nesmeyanov Institute of Organoelement Compounds
of Russian Academy of Sciences
(INEOS RAS)		 Здание ИНЭОС РАН
  • History
    • Historical background
    • Awards & Prizes
    • Museum of A.N.Nesmeyanov
    • Directors
    • Famous scientists
  • Scientific activity
    • Scientific Councils
    • Research areas
    • Conferences
    • Exhibitions
    • Inventions
  • Administration
    • INEOS Management
    • Scientific secretary
  • Divisions
    • Organometallic
    • Organoelement
    • Physical
    • Macromolecular
    • Other
  • Employees
  • Education
  • Our Services
  • Contacts

Divisions

  • Organometallic
  • Organoelement
  • Physical
  • Macromolecular
    • #301 (LMC)
    • #302 (LHP)
    • #304 (LOSC)
    • #308 (LSHP)
    • #310 (LPP)
    • #311 (LPCP)
    • #313 (LPM)
    • #314 (LSSP)
    • #316 (LHMC)
    • #318 (LPA)
    • #322 (LCB)
    • #324 (MHM)
  • Other

#311 Laboratory for Physical Chemistry of Polymers (LPCP)

  • Print

Head of Chair and Laboratory is Professor Alexei R. Khokhlov

 

Employees

Ph.D., senior researcher Barabanova A. I., Dr. Sc., leading researcher Blagodatskikh I.V., Ph.D., senior researcher Burova T.V., Dr. Sc. leading researcher Vorobiev M.M., junior researcher Vorozheikina A.V., research engineer Galiullin A. N., Ph.D., researcher Glagolev M. K., Dr. Sc., leading researcher Godovsky D. Yu., Ph.D., senior researcher Golovanov A. V., Ph.D., researcher Grigoriev T. E., Dr. Sc., leading researcher Grinberg V. Ya., researcher Grinberg N.V., Ph.D., senior researcher Davydova N.K., Ph.D., senior researcher Dubovik A. S., Ph.D., senior researcher Zefirov V.V., Ph.D., junior researcher Kazaryan P. S., Dr. Sc., leading researcher Kaznacheev A.V., Ph.D., researcher Kalinkin D. P., Dr. Sc., leading researcher Keshtov M.L., Ph.D., senior researcher Kizas O.A., Dr. Sc., leading researcher Komarov P.V., Dr. Sc., leading researcher Kuklin S.A., Ph.D., leading engineer Ledneva N.P., Ph.D., senior researcher Moskalets A.P., Ph.D., senior researcher Nikolaev A.Yu., Ph.D., leading engineer Onishchenko T.A., junior researcher Perepelkin E.I., junior researcher Pestrikova A. A., Ph.D., senior researcher Said-Galiev E.E., researcher Sergeev V.N., Ph.D., researcher Sinitsina O.V., Dr. Sc., leading researcher Sonin A.S., Ph.D., researcher Stakhanov A.I., Dr. Sc., leading researcher Talis A.L., junior researcher Tishchenko N. A., research engineer Khlopov S. A., Ph.D., senior researcher Chashchin I.S., junior researcher Shikin D. Ya.

 

Story

The Laboratory of Physical Chemistry of Polymers was organized in 1954. The organizer of the laboratory and its director until 1966 was Corresponding Member of the USSR Academy of Sciences, Professor S.R. Rafikov. From 1966 to 1991 The laboratory was headed by Professor S.A. Pavlova. Since 1991, the laboratory has been headed by Academician A.R. Khokhlov.

 

Research topics

  • Multiscale modeling of molecular systems.
  • Determination of symmetry patterns of structure and modeling of the structure of biomembrane components
  • Development of methods for the synthesis of new monomers and polymers, and the creation of innovative materials based on them, including solar photocells, stimuli-responsive polymer materials, omniphobic coatings, nanocomposites
  • Study of various processes and creation of new materials using supercritical fluids
  • Thermochemistry of macromolecules. Energy of cooperative order-disorder transitions in solutions and gels of synthetic polymers and biopolymers
  • Mineral and organic liquid crystals. Electro- and magnetooptics of mineral and organic liquid crystals
  • Modeling the kinetics of formation of peptide nanoparticles during enzymatic hydrolysis of polypeptides
  • Study of molecular-weight characteristics of polymers using gel permeation chromatography and light scattering methods. Study of structuring in polymer solutions

 

Grants and contracts for 2017-2024

  • 2017-2022 RSF 17-13-01359 “Creation of omniphobic polymer coatings in a supercritical carbon dioxide environment.” Head: Academician of the Russian Academy of Sciences Khokhlov A. R.
  • 2018-2021 RFBR 18-53-80066 BRICS_t “Development of efficient polymer solar cells with low losses based on non-fullerene low molecular weight acceptors.” Head: Academician of the Russian Academy of Sciences Khokhlov A. R.
  • 2018-2021 RFBR 18-53-53031 GFEN_a “New low-molecular perylene diimides as promising non-fullerene acceptors for highly efficient polymer solar photocells.” Head: Dr. Sc. Godovsky D.Yu.
  • 2018-2020 RFBR 18-53-45028 IND_a “New highly efficient wide-gap conjugated copolymers for use in organic solar photocells.” Supervisor: Ph.D. Nikolaev A.Yu.
  • 2020-2022 Grant of the Ministry of Education and Science of Russia 2020-1902-01-347 Fundamental principles for creating waste-free production of polymers and polymer materials with a programmable service life that meet modern environmental requirements (Polymers of the future)” Head: Academician of the Russian Academy of Sciences Khokhlov A. R.
  • 2020-2022 RFBR 20-03-00468A “Intelligent polyelectrolyte coatings for bioprostheses: production using subcritical technologies, structure and properties.” Supervisor: Ph.D. Chashchin I. S.
  • 2021-2022 RFBR 21-53-53037 GFEN_a “New efficient non-fullerene acceptors with absorption in the near-infrared region for highly efficient polymer solar photocells” Head: Dr. Sc. Keshtov M. L.
  • 2022-2023 RSF 22-23-00559 “Hybrid biomatrices with intelligent antibacterial coating based on Bos taurus xenopericardium and chitosan nanoparticles for cardiovascular surgery.” Supervisor: Ph.D. Chashchin I. S.
  • 2023-2024 RSF 23-23-00198 “Construction of chitosan derivatives that have an antimicrobial effect in weakly alkaline media and are compatible with albumin in solutions simulating blood plasma and interstitial fluid.” Head: Dr. Sc. Blagodatskikh I. V.
  • 2024-2025 RSF 24-23-00580 “New methods for modifying polymer gas separation membranes in a supercritical carbon dioxide environment.” Supervisor: Ph.D. Nikolaev A. Yu.
  • 2023-2026 RSF 24-43-00178 “Asymmetric non-fullerene acceptors for environmentally friendly, highly efficient large-area translucent organic solar cells.” Head: Academician of the RAS Khokhlov A.R.
  • 2024-2026 RSF 24-43-02039 “New asymmetric non-fullerene acceptors with low energy losses for highly efficient organic solar photocells.” Head: Dr. Sc. Keshtov M. L.

 

Key publications for 2021-2024

  • Malyshev M. D., Guseva D. V., Komarov P. V. Two-state nanocomposite based on symmetric diblock copolymer and planar nanoparticles: mesoscopic simulation // Mol. Syst. Des. Eng. – 2024. – Vol. 9. – P. 409-422. DOI:10.1039/d3me00176h
  • Malyshev M. D., Guseva D. V., Vasilevskaya V. V., Komarov P. V. Effect of nanoparticles surface bonding and aspect ratio on mechanical properties of highly cross-linked epoxy nanocomposites: mesoscopic simulations // Materials. – 2021. – Vol. 14(21). - P. 6637
  • DOI:10.3390/ma14216637
  • Komarov P. V., Malyshev M. D., Yang T.-C., Chiang C.-T., Liao H.-L., Guseva D. V., Rudyak V. Y., Ivanov V. A, Tung S.-H. Additive-induced ordered structures formed by PC71BM fullerene derivatives // Soft Matter. – 2021. – Vol.17(4), – P. 810-814. DOI:10.1039/D0SM02240C
  • Rabinovich A.L., Talis A.L. Structural unit for describing the non-crystallographic symmetry of hydrocarbon chains - components of phospholipid molecules // Izv. RAS. Ser. Phys. – 2021. – T. 85, No. 8, pp. 1116–1121. DOI: 10.31857/S036767652108024X
  • Talis A.L., Kucherinenko Ya.V. Non-crystallographic helices in polymers and close-packed metallic crystals determined by the 4-dimensional counterpart of the icosahedron // Acta. Crystallogr. B. Struct. Sci. Christ. Eng. Mater.—2023. – Vol. 79, No.1. P. 537—546. DOI: 10.1107/S2052520623009393
  • Talis A.L., Kraposhin V.S. Structural model of phase transitions in manganese determined by the closest spiral packing of tetrahedrons // Met. Sci. Heat Treat. – 2023. – Vol. 65, No. 1-2. P. 122-126. DOI: 10.1007/s11041-023-00901-6
  • Kuklin S. A., Safronov S. V., Fedorovskii O. Yu., Khakina E. A., Peregudov A. S., Ezernitskaya M. G., Komissarova E. A., Emelianov N. A., Uvarov M. N., Kulik L. V., Frolova L. A., Troshin P. A., Khokhlov A. R. New highly π-conjug ated bisalkynyl-linked oligomers of heteroatom-substituted perylene diimides: Optical and electronic properties and performance in perovskite solar cells // Organic Electron. – 2024. – Vol. 125. – P. 106978. DOI:10.1016/j.orgel.2023.106978
  • Keshtov M.L., Khokhlov A.R., Shikin D.Y., Alekseev V., Chayal G., Dahiya H., Singh M.K., Chen F.C., Sharma G.D. Medium bandgap nonfullerene acceptor for efficient ternary polymer solar cells with high open-circuit voltage // ACS Omega – 2023. – Vol.8(2). – P. 1989-2000. DOI:10.1021/acsomega.2c05141
  • Gribov P.S., Kondakova N.N., Il’icheva N.N., Stepanova E.R., Denisyuk A.P., Sizov V.A., Dotsenko V.D., Vinogradov D.B., Bulatov P.V., Sinditskii V.P., Suponitsky K.Yu., Il’in M.M., Keshtov M.L., Sheremetev A. B. Energetic Polymer Possessing Furazan, 1,2,3-Triazole, and Nitramine Subunits // Int. J. Mol. Sci. – 2023. – Vol. 24. – P. 9645. DOI:.3390/ijms24119645
  • Keshtov M.L., Konstantinov I.O., Kuklin S.A., Davydova N.K., Alekseev V.G., Xie Zh., Agarwal A., Ganesh D. Sharma. New wide-bandgap D–A polymer based on pyrrolo[3,4-b] dithieno[2,3-f:30,20-h]quinoxalindione and thiazole functionalized benzo[1,2-b:4,5-b0] dithiophene units for high-performance ternary organic solar cells with over 16% efficiency // Sustainable Energy & Fuels. Spectroscopy ‒ 2022. ‒ V.2. ‒ P. 682-692 DOI:10.1039/d1se01748a
  • Pengfei L., Wu F., Fang Y., Dahiya H., Keshtov M.L., Xu H., Agrawal A., Sharma G.D. Truxene π-Expanded BODIPY Star-Shaped Molecules as Acceptors for Non-Fullerene Solar Cells with over 13% Efficiency // Applied Energy Materials. ‒ 2022. ‒ V.5, No. 2. ‒ P. 2279-2289. DOI: 10.1021/acsaem.1c03781
  • Keshtov M.L. Konstantinov I.O., Khokhlov A.R., Ostapov I.E., Alekseev V.G., Xie Zh., Dahiya H., Sharma G.D. Synthesis of D-A copolymers based on thiadiazole and thiazolothiazole acceptor units and their applications in ternary polymer solar cells // Journal of Polymer Science. - 2022. - V.60. ‒ P. 2086-2099. DOI: 10.1002/pol.20220096
  • Kazaryan P. S., Godovsky D. Y., Keshtov M. L., Kondratenko M. S., Nekrasov A., Erokhin V. Red-Ox front propagation in polyaniline-polymer electrolyte system as a basis for spiking and rate-based neural networks and multibit ReRAM // Mater. Today Commun. – 2023. – Vol. 37. – P. 107186. DOI: 10.1016/j.mtcomm.2023.107186
  • Davydova N.K., Sergeev V.N., Peregudov A.S., Kuravina A.E., Sadykova V.S., Savinova T.S. Design, synthesis of novel N-substituted 6-piperazinomethyl-∆4-3,17-diketo-steroids and their antimicrobial activity evaluation // Curr. Org. Chem. – 2023. – Vol. 27(15). – P. 1265 – 1370. DOI:10.2174/0113852728262675230922050004
  • Mitrofanov A. Yu., Murashkina A. V., Barabanova A. I., Vorozheikina A. V., Zubavichus Y. V., Khokhlov A. R., Beletskaya I. P. Efficient recyclable Cu-catalysts for click reaction and chan-lam coupling based on copolymers of N-vinylimidazole with N-vinylcaprolactam // Molecular. Catalysis – 2023. – Vol. 541. – P. 112915. DOI:10.1016/j.mcat.2023.112915
  • Barabanova A I., Afanas`ev E. S., Molchanov V. S., Askadskii A. A., Filippova O. E. Unmodified silica nanoparticles enhance mechanical properties and welding ability of epoxy thermosets with tunable vitrimer matrix // Polymers – 2021. - Vol. 13918. - P. 3040; DOI: 10.3390/polym13183040
  • Kazaryan P. S., Gritsevich D. K., Gallyamov M. O., Pestrikova A. A., Gulin A. A., Kirianova A. V., Kondratenko M. S. Dependence of slippery and elastic properties of thin polymer films on the grafted flexible sidechain amount // Langmuir - 2023. – Vol. 39(20). – P. 7029. DOI:10.1021/acs.langmuir.3c00238
  • Kletnov D.A., Biriukov K.O., Nikolaev A.Yu., Afanasyev O.I., Chusov D.A. Effect of carbon dioxide on bromantane synthesis by reductive amination without external hydrogen source // INEOS OPEN - 2023. DOI:10.32931/io2307a
  • Budaev A.A., Borovkova N.V., Fayn A.M., Nikolaev A.Yu., Makarov M.S., Storozheva M.V., Skuratovskaya K.I., Vaza A.Yu., Fomicheva I.V., Chernen'kaya T.V., Kanibolotskiy A.A. Evaluation of the effectiveness of allogeneic tendon graft sterilization with supercritical carbon dioxide // Bulletin of the Medical Institute "REAVIZ" (rehabilitation, doctor and health). – 2023. – Vol.13, No. 4. – P. 145-153. DOI: 10.20340/vmi-rvz.2023.4.TX.2
  • Grinberg V.Y., Burova T.V., Grinberg N.V., Tikhonov V.E., Dubovik A.S., Orlov V.N., Plashchina I.G., Usov A.I., Khokhlov A.R. Energetics and mechanism of complexation between β-lactoglobulin and oligochitosan.//Food Hydrocoll. – 2023. – Vol. 134. – P. 108021. DOI: 10.1016/j.foodhyd.2022.108021
  • Burova T.V., Grinberg N.V., Dubovik A.S., Plashchina I.G., Usov A.I., Grinberg V.Y. Soluble complexes of ovalbumin with fucoidan: Energetics of binding, protein stability and functional properties // Food Hydrocoll. – 2023. – Vol. 142. – P. 108767. DOI: 10.1016/j.foodhyd.2023.108767
  • Grinberg V.Y., Burova T.V., Grinberg N.V., Dubovik A.S., Tikhonov V.E., Moskalets A.P., Orlov V.N., Plashchina I.G., Khokhlov A.R. Chitosan polyplexes: Energetics of formation and conformational changes in DNA upon binding and release // Int. J Biol. Macromol. – 2023. – Vol. 250. – P. 126265. DOI: 10.1016/j.ijbiomac.2023.126265
  • Golovanov A.V. On the issue of hydrodynamic instability of nematics in a magnetic field. III. Taking into account the inertial term in the equation of motion in the model of magnetohydrodynamic domains for transverse bending deformation // Crystallography - 2023. - T. 68, No. 4. - P. 600-606. DOI: 10.31857/S0023476122600434
  • Pozhidaev E.P., Kuznetsov A.V., Kaznacheev A.V., Torgova S.I., Tkachenko T.P. Liquid crystal electro-optical modulator of the sub-megahertz range // Liquid crystals and their practical use - 2023. - T. 23, No. 4. - P. 94-102. DOI: 10.18083/LCAppl.2023.4.93
  • Vorob’ev M.M., Açıkgöz B.D., Güler G., Golovanov A.V., Sinitsyna O.V. Proteolysis of Micellar β-Casein by Trypsin: Secondary Structure Characterization and Kinetic Modeling at Different Enzyme Concentrations // Int. J. Mol. Sci. – 2023. – Vol. 24, No. 4. – P. 3874. DOI: 10.3390/ijms24043874
  • Blagodatskikh I.V., Vyshivannaya O.V., Tishchenko N.A., Orlov V.N., Tikhonov V.E., Bezrodnykh E.A., Ezernitskaya M.A., Khokhlov A.R. Complexation between chitosan and carboxymethyl cellulose in weakly acidic, neutral, and weakly alcaline media // International Int. J Biol. Macromol – 2023. – Vol. 243. – P. 125277. DOI: 10.1016/j.ijbiomac.2023.125277
  • Barabanova A. I., Blagodatskikh I.V., Vyshivannaya O.V., Muranov A.V., Peregudov A.S., Khokhlov A.R. Synthesis, thermoresponsive behavior, and catalytic properties of amphiphilic diblock copolymers of N-vinylcaprolactam and N-vinylimidazole // Polym. Sci. Ser. A – 2021. - Vol. 63(4). – P. 382-399. DOI: 10.1134/S0965545X21040027
  • Perepelkin E.I., Sinolits M.A., Badun G.A., Chernysheva M.G., Anuchina N.M., Abramchuk S.S., Levin E.E., Bakuleva N.P., Popov D.A., Chaschin I.S. Composite chitosan-based nanoparticles as a basis for innovative antimicrobial coating for bioprosthesis: preparation and application using carbonic acid as a “green” self-neutralizing solvent // Eur. Polym. J. – 2023. – Vol. 193. – P. 112104. DOI: 10.1016/j.eurpolymj.2023.112104

 

Patents for 2023

  • 2023 N-Substituted derivatives of 6α-piperazinomethylandrost-4-ene-3,17-dione with antimicrobial activity, and a method for their preparation. Authors: Sergeev V.N., Davydova N.K., Sadykova V.S., Savinova T.S. RF Patent No. 2807924, 11.21.2023
  • 2023 Composite carbon airgel containing metal oxide airgel and method for its preparation. Authors: Elmanovich I.V., Zefirov V.V. RF Patent No. 2795582, 05.05.2023
  • 2023 Method and installation for sterilization of tendon grafts. Authors: Budaev A.A., Nikolaev A.Yu., Khokhlov A.R., Bondarev V.B., Borovkova N.V., Fain A.M., Chernenkaya T.V., Makarov M.S., Vaza A.Yu., Andreev Yu.V., Storozheva M.V. RF Patent No. 22802139, 08.22.2023
  • 2023 Neural networks and resistive memory based on polyaniline in combination with an ion-conducting polymer and a method for their manufacture. Authors: Godovsky D.Yu. Application for patent of the Russian Federation No. 2018 126 189 A 09.08.2023

 

Chapters in books 2022

  • Samoilova N.A., Krayukhina M.A., Vyshivannaya O.V., Blagodatskikh I.V. Nanosilver-Labeled Polymer Glycoconjugates for Specific Lectins Sensing. Advances in Nanotechnology. Chapter 6, Ed. by Bartul Z. and Trenor J. (Nova Science Publishers, Inc., US, 2022, 209 pages, ISBN: 979-8-88697-171-2), pp. 127–148

 

Books (monographs) 2023

  • Mayfat D.A., Komarov P.V. Examples of solving the problems in theoretical mechanics: Kinematics and dynamics of a material point: a textbook. - Tver: Tver State University, 2023. - 82 p. ISBN 978-5-7609-1819-2, electronic edition

 

Links to positive and neutral mentions of laboratory staff in the media

Interview with the Izvestia newspaper: https://iz.ru/1537433/andrei-korshunov/skolzko-mozhno-uchenye-sozdali-samoochishchaiushchiesia-pokrytiia

 

Additional information about the laboratory and its director can be found on the website https://polymer.phys.msu.ru

© INEOS RAS, 2011–2023. Russia, Moscow, 119334, Vavilova St., 28, bld. 1. Tel. +7 (499) 135-92-02, fax +7 (499) 135-50-85, e-mail  

Contact webmasterINEOS mail server

#311 (LPCP)