Staff:
Afanas'ev E.S., Goleneva L.M., Kazantseva V.V., Kovriga O.V., Kurskaya E.A., Markov V.A., Petunova M.D.
Research area:
Synthesis of the functionally substituted [2.2]paracyclophanes, their usage for the preparation of the chiral catalysts, coordination compounds and polymers.
Grants:
1. Conformation of single macromolecules and their self-organizing directed by external influences. Principle Investigator prof. Askadsky А.А
2. Project P-7. 2009 — 2010. «Elaboration of the chemo-, egion- and stereoselective techniques for the synthesis of novel planar chiral quinoid and semiquinoid structures based on [2.2]paracyclophane» (Principle Investigator PhD Sergeeva E. V.) in the frame of the Presidium RAS Fundamental Investigations Program «Elaboration of the methods of the preparation of chemical compounds and creation of novel materials» (Program coordinator academician V. A. Tartakovsky) by direction «Development of the methodology of organic synthesis and creation of compounds with valuable applied properties» (the Head of the Program Direction academician Yu. N. Bubnov).
3. Project RFBR № 10-03-00898-а. 2010 — 2011. «New hybrid optical materials based on transition and rare earth metal complexes with [2.2]paracyclophane derivatives: synthesis, peculiarities of electron structure and luminescent properties», Principle Investigator PhD Puntus L. N., Institute of Radioengineering and Electronics RAS)
Recent publications:
1. А.А. Askadski., L.M. Goleneva, K.A. Bychko, O.V. Afonicheva Synthesis and investigation of mechanical behavior of the gradient-modulus polymeric materials based on polybutadienediol rubber. //Polymer Sci. 2008. A50. №7. P.781791.
2. N. V. Vorontsova, V. I. Rozenberg, E. V. Sergeeva, E. V. Vorontsov, Z. A. Starikova, K. A. Lyssenko, H. Hopf, Symmetrical Tetrasubstituted [2.2]Paracyclophanes: their Systematization and Regioselective Synthesis of Several Types of Bis-Bifunctional Derivatives by Double Electrophilic Substitution. //Chem. Eur. J. 2008. 14. P.4600-4617.
3. Goleneva L.M., Askadskii А.А., Petunova M.D., Kovriga O.V. Gradient-modulus polyurethaneisocyanurate materials based on polypropyleneglycol as prepared by one step processes. //Plasticheskie Massy. 2008. №6. P. 17 — 22. (Rus).
4. M.D. Petunova, A.A. Askadskii, L.V. Luchkina, O.V. Kovriga. Synthesis and Propertis of Polyisocyanurate Networks Based on 2,4-Tolyene Diisocyanate. // Polymer Sci.. 2009. А51. № 5. Р. 576 — 582.
5. А.А. Askadski., V.A. Markov, A.V. Golovanov, O.V. Pachneva, M.N. Popova, O.V. Kovriga, O.L. Lependina, V.V. Kazanzeva, М.I. Buzin, А.А. Korlukov Analyses of Stress Relaxation in the Nonlinear Region of Mehanical. //Polymer Sci.. 2009. А51. № 5. Р. 838 — 844.
6. L.М. Goleneva, А.А Askadskii. One-Sage Synthesis of Network Poly(urethane-isocyanurate) Polymers. //Polymer Sci. 2009. С51. № 1. P. 26 — 34.
7. Samoilova N., Kurskaya E., Krayukhina M., Askadskii A., Yamskov I..
Copolymers of Maleic Acid and Their Amphiphilic Derivatives as Stabilizers
of Silver Nanoparticles. //J. Phys. Chem., 2009. B113. №11. Р. 3395-3403.
8. Marchenkov А. V., Goleneva L.M, Askadskii Аndr. Аl., Kurskaya Е. А., Askadskii Аl. Аndr. Polymeric paint and varnish composition based on polycarbonate. //Plasticheskie Massy. 2009. №. 6. Р. 45 — 49. (Rus).
9. N. V. Vorontsova, G. S. Bystrova, D. Yu. Antonov, A. V. Vologzhanina, I. A. Godovikov, M. M. Il’in, Novel ligands based on bromosubstituted hydroxycarbonyl [2.2]paracyclophane derivatives: synthesis and application in asymmetric catalysis. //Tetrahedron: Asymmetry. 2010. 21. Р. 731-738.
10. Elena V. Sergeeva, Ivan A. Shuklov, Dmitrii Yu. Antonov, Natalia V. Vorontsova, Evgenii V. Vorontsov, Zoya A. Starikova, Michail M. Il’in, Valeria I. Rozenberg, Resolution approaches to enantiomers of 4-formyl[2.2]paracyclophane. //Tetrahedron: Asymmetry. 21. 2010. Р. 1004-1010.
11. E.S. Afanas'ev, M.D. Petunova, L.M. Goleneva, A.A. Askadskii, T.P. Klimova, and T.A. Babushkina. The effect of the conditions of formation of crosslinked polyurethane on the degree of crosslinking and mechanical characteristics //Polymer Sci. 2010. A. Vol. 52. №12. P. 1318 - 1326.
Recent patents:
А.Askadsky, Е. Kurskaya, N.Samoilova, I.Yamskov. Composition as a bactericidal agent, the method of obtaining the material on its basis and the macroporous bactericidal substance based on this composition. Favourable decision 2009128492/15(039546) from 01.06.2010 for 2009128492 RF patent application from 23.07.2009.
