RAS FASO RFBR RSF
  • Русский
INEOS Logo A. N. Nesmeyanov Institute of Organoelement Compounds
of Russian Academy of Sciences
(INEOS RAS)
Здание ИНЭОС РАН
  • History
    • Historical background
    • Awards & Prizes
    • Museum of A.N.Nesmeyanov
    • Directors
    • Famous scientists
  • Scientific activity
    • Scientific Councils
    • Research areas
    • Conferences
    • Exhibitions
    • Inventions
  • Administration
    • INEOS Management
    • Scientific secretary
  • Divisions
    • Organometallic
    • Organoelement
    • Physical
    • Macromolecular
    • Other
  • Employees
  • Education
  • Our Services
  • Contacts

Divisions

  • Organometallic
  • Organoelement
    • #107 (LPSMS)
    • #109 (LFOS)
    • #112 (LOPC)
    • #114 (LOFC)
    • #115 (LPAOC)
    • #116 (LAC)
    • #126 (LEC)
    • #128 (LHROC)
    • #130 (LSBAHC)
    • #135 LCC
  • Physical
  • Macromolecular
  • Other

#109 Laboratory for Fine Organic Synthesis (LFOS)

  • Print

 

Head of the laboratory: Professor, Dr.Sc., Valery N. KALININ

 

Staff:

Vakhmistrov V.E., Zaitsev A.V., Kas'yanova R.Sh., Koldobsky A.B., Makarenkov A.V., Moiseev S.K., Ol’shevskaya V.A., PetrushkinaE.A., Ponomarev A.B., Rys E.G., Samarskaya A.S., Sandulenko I.V., Cherepanov I.A., ShilovaO.S., Shostakovskii M.V.

 

Research fields:

  • Medicinal Chemistry
  • Organometallics and Transition Metal Complexes in Organic Synthesis
  • Chemistry of Carboranes
  • Meso-ionic compounds
  • Transition Metal Complex Catalysis

 

 

Recent main publications:

  1. A. Kreienbrink, M. B. Sarosi, E. G. Rys, P. Lonnecke, E. Hey-Hawkins. Carbaborane-Substituted 1,2-Diphosphetanes. Angew. Chem. Int. Ed., 50, (20), 4701-4703 (2011).
  2. A.B.Koldobskii, E.V.Solodova, I.A.Godovikov, P.V.Verteletskii, V.N.Kalinin. 1-Bromo-2-trifluoroacetylcyclobutenes as novel building blocks for the construction of trifluoromethyl substituted heterocycles. Part 3: Synthesis of trifluoromethylsubstituted pyridines, condensed with cyclobutene moieties. // J. Fluor. Chem., 131, (8), 873-878 (2010).
  3. A.B.Koldobskii, N.P.Tsvetkov, E.V.Solodova, P.V.Verteletskii, I.A.Godovikov, V.N.Kalinin. Synthesis of novel β-dialkylamino-α,β-unsaturated trifluoromethyl ketones containing cyclobutene fragment and their reactions with organolithium and Grignard reagents. // Tetrahedron, 66, (19), 3457-3462 (2010).
  4. V.A.Ol’shevskaya, A.N.Savchenko, A.V.Zaitsev, E.G.Kononova, P.V.Petrovskii, A.A.Ramonova, V.V.Tatarskiy Jr., M.M.Moisenovich, V.N.Kalinin, A.A.Shtil. Novel Metal Complexes of Boronated Chlorine e6 for Photodynamic Therapy. // J. Organomet. Chem., 694, 1632-1637 (2009).
  5. V.A.Ol’shevskaya, R.G.Nikitina, A.N.Savchenko, M.V.Malshakova, A.M.Vinogradov, G.V.Golovina, D.V.Belykh, A.V.Kutchin, M.A.Kaplan, V.N.Kalinin, V.A.Kuzmin, A.A.Shtil. Novel boronated chlorin e6-based photosensitizers: Synthesis, binding to albumin and antitumour efficacy. // Bioorg. Med. Chem., 17, 1297-1306 (2009).
  6. V.N.Kalinin, S.N.Lebedev, I.A.Cherepanov, I.A.Godovikov, K.A.Lyssenko, E.Hey-Hawkins. 4-Diphenylphosphinosydnone Imines as Bidentate Ligands. // Polyhedron, 28, 2411-2417 (2009).
  7. I.A.Cherepanov, S.N.Lebedev, A.S.Samarskaya, I.A.Godovikov,Yu.V.Nelyubina, V.N.Kalinin. 4-Thio derivatives of sydnone imines. // Mendeleev Commun., 19, 322-323 (2009).
  8. E.G.Rys, P.Lonnecke, S.Stadlbauer, V.N.Kalinin, E.Hey-Hawkins. Chiral functionalized bisphosphine ligands: Transition metal complexes of 1,2-bis(tert-butylchlorophosphido)-1,2-dicarba-closo-dodecaborane(12). // Polyhedron, 28, 3467-3472 (2009).
  9. I.V.Evsikova, S.K.Moiseev, P.V.Petrovskii, V.N.Kalinin. Carbonate derivatives of 14b-hydroxycodeine. // Russ. Chem. Bull., Int. Ed., 57, (8), 1773-1774 (2008), (Engl. Transl.).
  10. S.E.Lyubimov, V.A.Davankov, P.V.Petrovskii, E.Hey-Hawkins, A.A.Tyutyunov, E.G.Rys, V.N.Kalinin.  Chiral Carborane-Derived Thiophosphites: New Generation of Ligands for Rh-catalyzed asymmetric hydrogenation. // J. Organometal. Chem., 693, 3689 (2008).
  11. S.E.Lyubimov, V.N.Kalinin, A.A.Tyutyunov, V.A.Ol’shevskaya, Yu.V.Dutikova, Chan Seong Cheong, P.V.Petrovskii, A.S.Safronov, V.A.Davankov. Chiral Phosphites Derived from Carboranes: Electronic Effect in Catalytic Asimmetric Hydrogenation. // Chirality, 21, (1), 2-5 (2008).

 

Recent patents:

  1. V.A.Ol’shevskaya, A.V.Zaitsev, N.D.Chkanikov, A.L.Sigan, V.N.Kalinin. Carboranyl Derivatives of Fluorinated Porphyrines and Their Metal Complexes: Photosensibilisative Properties and Preparations. // Rus. Patent No. 2402554.
  2. V.A.Ol’shevskaya, A.N.Savchenko, A.V.Zaitsev, V.N.Kalinin, A.A.Shtil, M.A.Kaplan, R.G.Nikitina, A.A.Ramonova, M.M.Moisenovich, I.I.Agapov. Chlorine е6 13(1)-N-{2-[N-(closo-Monocarbadodecabora-1-yl)methyl]aminoethyl}-amide-15(2),17(3)-dimethyl Ester Derivatives with Enhances Antitumor Activity. // Rus. Appl. No.  2009115755 (April 27, 2009). Approved: July 06, 2010.

© INEOS RAS, 2011–2023. Russia, Moscow, 119334, Vavilova St., 28, bld. 1. Tel. +7 (499) 135-92-02, fax +7 (499) 135-50-85, e-mail  

Contact webmasterINEOS mail server

#109 (LFOS)