Staff:
Akadzieva I.M., Aleksanyan D.V.., Aleksenko V.Yu., Artyushin O.I., Baulina T.V., Bodrin G.V., Bihovskaya O.V., Vinogradova N.M., Genkina G.K., Goryunov E.I., Kalyanova R.M., Kozlov V.A., Kudryavtsev I.Yu., Makarov M.V., Matveev S.V., Matveeva A.G., Matveeva E.V., Morgalyuk V.P., Nifant'ev E.E., Ostapchuk P.N., Pasechnik M.P., Savin E.D., Frolova N.G., Chaadaeva A.B., Churusova S.G., Sharova E.V.
Field of Research:
Synthesis of new types of organophosphorus compounds, study of their structure, reactivity, and possibility of practical application.
Design of new types of organophosphorus extractants and sorbents for partitioning and concentrating actinides in the reprocessing of highly radioactive wasted of nuclear power plants.
Design of original types of organophosphorus bioregulators and materials based on wood slash.
Study of acid--base and complex-forming properties of organophosphorus compounds. Stucture of species in solutions, hydrogen bonding, issues of solvatation and tautomerism.
Current Grants and Contracts:
1. Project "Desing and innovative development of phosphorus derivatives of dihydroquercetin and other products containing in parch" in the context of the P-5 Program of the Presidium of the RAS «Fundamental Sciences for Medicine». The head of the project: Corresponding member of the RAS, prof. E.E. Nifantiev. (In cooperation with the Moscow State Pedagogical University and Russian Oncology Center, Russian Academy of Medical Sciences).
2. Project «Development of fundamentals for fir processing by disintegration using cavitator-type devices within the Basic Research Program OKhMN-05 of the Department of Chemisrty and Material Science, RAS "Design of new products from mineral and organic feedstock". The head of the project: Corresponding Member of the RAS, prof. E.E. Nifantiev. (In cooperation with the Moscow State Pedagogical University).
3. Project "The methods for the synthesis of new phosphorus- and nitrogen-containing ligands" within the P-7 Basic Research Program of the Presidium of the RAS "Development of methods for preparing chemical compounds and design of new materials" (Subprogram "Development of methodology of organic synthesis and design of compounds showing properties valuable for practical application"). The head of the project: Prof., D.Sc. I.L. Odinets (In cooperation with the Laboratory of Thioorganophosphorus Compounds).
4. RFBR grant 08-03-00586-a "New types of hydrophosphoryl compounds and their complexes with transition metals" The leader: Prof., D.Sc. Yu.А. Ustynyuk. (in cooperation with the Moscow State University).
History of the Laboratory:
Laboratory of Organophosphorus Compounds (LOPhC) was included in a pool of laboratories of the Institute of Organic Chemistry, Russian Academy of Sciences, that provide a basis for the foundation in 1954 of the Institute of Organoelement Compounds. The laboratory was headed by Academician Martin I. Kabachnik (1908-1997) since its foundation till 1991.
Martin I. Kabachnik in office (INEOS, 1997)
Martin I. Kabachnik and Tatyana A. Mastryukova (INEOS)
In 1991–2000, the laboratory was headed by Corresponding Member of the RAS, Doctor of Science (Chem.), Professor T.A. Mastryukova (1925-2006).
Famous chemists worked in the laboratory within different years:
Professor, D. Sc. (Chemistry) S.T. Ioffe,
Professor, D. Sc. (Chemistry) T.Ya. Medved’,
Professor, D. Sc. (Chemistry) V.A. Gilyarov,
Professor, D. Sc. (Chemistry), E.N. Tsetkov,
Professor, D. Sc. (Chemistry) N.N. Bubnov,
Professor, D. Sc. (Chemistry), N.N. Godovikov,
Professor, D. Sc. (Chemistry) Yu. M. Polikarpov.
Selecta by M.I. Kabachnik "Chemistry of organophosphorus compounds" (in 3 volumes) were published in 2008--2009 in Nauka publising house.
Cooperations:
Vernadskii Institute of Geochemistry and Analytical Chemistry Russian Academy of Science;
Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Science;
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Science;
Department of Chemistry, Lomonosov Moscow State University;
Department of Chemistry, Moscow Pedagogical State University;
Department of Chemistry, Karazin Kharkov National University (Kharkov, Ukraine);
Department of Chemistry, Gumilev Europe-Asian National University (Kokshetau, Kazakhstan);
List of main publications over 2008—2010:
1. I.G. Tananaev, A.A. Letyushov, A.M. Safiulina, I.B. Goryunova, T.V. Baulina, V.P. Morgalyuk, E.I. Goryunov, L.A. Gribov, E.E. Nifantiev, B.F. Myasoedov, «Search Strategy for New Efficient Organophosphorus Extractants for Concentrating Radionuclides», Dokl. Chem (Engl. Transl.), 2008, 422, Part 2, 260-264.
2. A.G. Matveeva, P.S. Lemport, L.A. Leites, R.R. Aysin, A.V. Vologzhanina, Z.A. Starikova, M.P. Passechnik, E.E. Nifant’ev. «Lanthanide(III) complexes with phosphoryl containing 1,8-naphthyridine: Crystal structures and vibrational spectra», Inorg. Chim. Acta, 2009, 362, 3187–3195.
3. A.M. Safiulina, E.I. Goryunov, A.A. Letyushov, I.B. Goryunova, S.A. Smirnova, A.G. Ginzburg, I.G. Tananaev, E.E. Nifant'ev, B.F. Myasoedov, «Effect of аnomalous аryl strengthening in the series of N-phosphorylureas», Mendeleev Commun., 2009, 19, № 5, 263-265.
4. A.G. Matveeva, A.S. Peregudov, E.I. Matrosov, Z.A. Starikova, S.V. Matveev, and E.E Nifant’ev. «Structure and dynamic behaviour of lanthanide nitrate complexes with bis(diphenylphosphorylmethyl)mesitylene in solution. The nature of unexpected 31P NMR spectra», Inorg. Chim. Acta, 2009, 362, 3607-3616.
5. V.P. Morgalyuk, S.N. Kalmykov, E.I. Goryunov, P.V. Petrovskii, I.G. Tananaev, E.E. Nifant'ev. «Synthesis of template sorbent for the extraction of Am(III) from nitric acid solutions», Mendeleev Commun., 2009, 19, № 5, 266-267.
6. A.G. Matveeva, P.S. Lemport, M.P. Passechnik, R.R. Aysin, L.A. Leites, E.E. Nifant’ev, «Coordination of 2-phosphorylalkyl-substituted 1,8-naphthyridines in complexes with lanthanide nitrates», Russ. Chem. Bull., Int. Ed., 2009, v. 58, № 7, 1416-1422.
7. E.I. Goryunov, I.B. Goryunova, T.V. Baulina, P.V. Petrovskii, E.I. Matrosov, K.A. Lyssenko, M.S. Grigor’ev, A.M. Safiulina, V.P. Morgalyuk, A.A. Letyushov, I.G. Tananaev, E.E. Nifantiev, B.F. Myasoedov, «Synthesis, properties, complexing and extraction properties of N-diphenylphosphorylureas and related compounds», Ross. khim. zhurn., 2010, 54, № 3, 45-55.
8. N.G. Frolova, E.D. Savin, E.I. Goryunov, K.A. Lyssenko, Yu.V. Nelyubina, P.V. Petrovskii, E.E. Nifantiev, «Addition of Bis(pentafluorophenyl)phosphinous Acid to Compounds with Activated C=C Bond as a Method for the Synthesis of First Tertiary P,P-Bis(pentafluorophenyl)phosphine Oxides», Dokl. Chem (Engl. Transl.), 2010, 430, Part 1, 18-23.
9. T.V. Baulina, P.V. Petrovskii, E.I. Goryunov, E.E. Nifantiev, «Reactions of Phosphonic and Phosphoric Dichlorides with Sodium Cyanate as a General Synthesis Method of Phosphoryl Diisocyanates», J. Gen. Chem. (Engl. Transl.), 2010, 80, № 5, 1039-1040.
10. E.I. Matrosov, E.I. Goryunov, T.V. Baulina, I.B. Goryunova, P.V. Petrovskii, E.E. Nifantiev, «First Complexes of N-Diphenylphosphorylureas with Actinides and Lanthanides: Synthesis and Structure», Dokl. Chem (Engl. Transl.), 2010, 432, Part 1, 136-139.
Patents over 2008—2010:
1. E.E. Nifantiev, M.P. Koroteev, G.Z. Kaziev, T.S. Kukhareva, O.S. Zhukova, Z.S. Smirnova. Remedy showing antitumor activity and method for preparing thereof. Russian Federation patent no. 2349317, Mar 20, 2009.
2. E.E. Nifantiev, A.T. Teleshev, M.P. Koroteev, G.Z. Kaziev. Method for integrated processing of larch wood. Russian Federation patent no. 2361871, Jul 20, 2009.
Key papers of the laboratory in earlier years (1990s — 2000s):
1. М.I. Kabachnik, «Steric aspects of selectivity of organophosphorus extractants», Heteroatom. Chem., 1991, V. 2, № 1, p. 1–10.
2. F.I. Bel’skij, Yu.M. Polikarpov, М.I. Kabachnik, «Cyclopendant ligands », Russ. Chem. Rev. (Engl. Transl.), 1992, v. 61, № 2, pp. 415–455.
3. М.I. Kabachnik, L.S. Zakharov, E.I. Goryunov P.V. Petrovskii, G.N. Molchanova, T.M. Shcherbina, «Reversible transformations of diastereomers in a system with three chiral atoms », Dokl. Chem (Engl. Transl.), 1996, v. 347, № 6, pp. 770—773.
4. A.G. Matveeva, M.P. Passechnik, P.V. Petrovskii, S.V. Matveev, S.A. Pisareva, «Amino-substituted gem-diphosphonic acids: dissociation mechanism and structure of species in aqueous solutions», Russ. Chem. Bull. (Engl. Trans.), 2000, v. 49, № 6, 1045–1058.
5. M.P. Passechnik, A.G. Matveeva, S.V. Matveev, «Amino-substituted gem-diphosphonic acids: structure of complexes with cations of divalent metals in aqueous solutions», Russ. Chem. Bull., (Engl. Trans.), 2001, v. 50, № 4, 697–705.
6. E.I. Goryunov, G.N. Molchanova, I.B. Goryunova, T.V. Baulina, P.V. Petrovskii, V.C. Mikhailovskaya, A.G. Buyanovskaya, E.E. Nifant’ev, «Catalytic Method for the Synthesis of Phosphoryl Isocyanates», Russ. Chem. Bull. (Engl. Trans.), 2005, v. 54, No 11.
7. E.E. Nifant’ev, I.Yu. Kudryavtsev, E.I. Goryunov, I.B. Goryunova, G.N. Molchanova, P.V. Petrovskii, O.P. Korobeinichev, A.G. Shmakov, V.M. Shvartsberg, D.A. Knyaz’kov, «Novel ozone-friendly organophosphorus fire suppressants», XIV International Conference on Chemistry of Phosphorus Compounds. Kazan, Russia, June 27 - July 1, 2005. Book of Abstracts, 2005, Р53.
8. V.P. Morgalyuk, A.M. Safiulina, I.G. Tananaev, E.I. Goryunov, I.B. Goryunova, G.N. Molchanova, T.V. Baulina, E.E. Nifantiev, B.F. Myasoedov, «N-diphenylphosphoryl-N'-alkylureas as new type of extractants for actinoids concentration», Dokl. Chem., (Engl. Trans.), 2005, v. 403, part 1, 126-128.
9. T.V. Baulina, I.B. Goryunova, P.V. Petrovskii, E.I. Matrosov, E.I. Goryunov, E.E. Nifantiev, «"One-pot" method of synthesis of N-diphenylphosphorylureas», Dokl. Chem., (Engl. Trans.), 2006, v. 409, p.2, 129-132.
10. E.I. Goryunov, E.E. Nifantiev, B.F. Myasoedov, «Method of preparing N-diphenylphosphoryl-N'-alkyl(С6-С10)ureas», RF Patent no. 2296768, April 10 , 2007, Bull. izobr., no. 10 (2007)
11. G.V. Bodrin, P.S. Lemport, S.V. Matveev, P.V. Petrovskii, E.E. Nifant’ev, «The first application Frienländer reaction for the synthesis of [1,8]naphthyridine derivatives containing phosphorus», Mend. Commun., 2007, v. 17, № 1, 25–26.