Amphiphilic cyclolinear organosilicon polymer able to the self-organization in mass and monomolecular films Langmuir - Blodgett, the liquid crystalline stereoregular organosilicon cycle monomer compounds and the comb-like liquid crystalline polymers able to the polymesomorphic transitions, polycycle organosilacycloalkanes and organosilaoxycycloalkanes, as the precursor of silicon carbid and silicon carbide oxide ceramics.
It is carry out the preparation of cyclolinear organosilicon polymers contents the hydrophilic and hydrophobic fragments: the cycle and bridge in the main cyclolinear polymethylsiloxane chain. It is found critical correlation between the hydrophilic and hydrophobic fragments in methylsilacycloalkanes units, which the monomolecular films were formed of the thickness approximately 10Å on the boundary water/air. The liquid crystalline comb-like cyclolinear polymers were synthesized with the side mesogenic groups which the formation monomolecular films Langmuir on the surface water.
1. N.N.Makarova, Yu.K.Godovsky, B.D.Lavrukhin«The synthesis and structures cyclolinear polyorganosiloxanes» Polymer science Ser A. 1995 V.37А. №3. с.373-375.
2. N.N.Makarova, Yu.K.Godovsky “Liquid-crystalline cyclochain organosilicon compounds” Progr.Polym.Sci., 1997 . V.22. p.1001-1051.
3.Yu.K.Godovsky, N.N.Makarova, E.V.Matukhina «Mesophase behavior and structure of mesophases in cyclolinear polyorganosiloxanes». Amer.Chem.Soc. Symp. ser., Silicones and Silicone-Modified materials.2000. v.729. p.98-114.
4. Yu.K.Godovsky, S.I.Belousov, N.N.Makarova, G.Brezesinski, H.Mohwald, T.R.Jensen, K.Kjaer, Nonlinear Optics, Quantom Optics (Special Issue “Smartand Functional Materials”) “Smart” polysiloxane monolayers and self-organized ultrathin films. Nonlinear Optics. Quantum Optics.2004.v.31.p.31-44.
5.N.N.Makarova, I.M.Petrova, L.M.Volkova, A.V.Kaznacheev, П.В.Петровский, A.M.Scherbina, S.N.Chvalun,Yu.K.Godovsky. The synthesis and properties new stereoregular liquid crystaline phenylcyclotetrasiloxanes. Изв.РАН. сер.хим.2004.№9.с.1902-1911.
6. Е.V.Matukhina, Е.Е.Аntipov, N.N.Makarova,Yu.K.Godovsky. Structure of ordered phases in hexylphenylsiloxane copolymers. Polymer science Ser A.2005. Т.47А. №9. с.1660-1671.
7. N.N.Makarova, I.M.Petrova, T.V.Vlasova, P.V.Petrovsky “ The synthesis methylcyclotetra(hexa)siloxanes with different reactivity groups at the same atom silicon” Russian Chem. Bull.Inter.Ed. 2006. v.55. №6. p.604-611.
8.N.N.Makarova, Ya.V.Zubavichus, P.V.Petrovsky, A.I.Buzin, A.V.Kaznacheev, T.V.Vlasova. «Self-organizing cyclolinear methylcyclohexasiloxane polymers carrying reactive vinyl groups» Polymer science Ser A. 2007. V.49.№11. с.1173-1182.
9. N.N.Makarova, А.V.Каznacheev, P.V.Petrovsky, I.M.Petrova “The synthesis and properties liquid crystal methylcyclohexasiloxane polymers with side mesogenic cyanobiphenyl groups”.Liquid crystals and their application. 2008. Выпуск 3 (25). p.12-22.
10. D.V.Anokhin, R.I.Gearba, Yu.K.Godovsky, N.N.Makarova, R.I.Ivanov, W.Bras, D.A.Ivanov. “Structure and phase behavior of disk-necklace polymer: cyclolinear polymethylsiloxane” Polymer 2007 V.48. N16. p.4837-4848.
11.N.N.Makarova, T.V.Astapova, N.V.Chizhova, I.M.Petrova «Cyclolinear and polycycle poly- and copolyorganocyclecarbosilanes as preceramic matrix for non-oxygen silicon carbide ceramic and method them preparation» Pat.Russia № 2291879 (2007) .
12. N.N.Makarova, T.V.Astapova, N.V.Chizhova, I.M.Petrova «Полициклические поли- и сополиорганоциклокарбосилоксаны, как предкерамические матрицы для кремнийкарбидоксидной керамики». Pat.Russia № 2291878 (2007).
