Волошин Ян Зигфридович

профессор, доктор химических наук,

заведующий лабораторией алифатических борорганических соединений

 

(тел. (499) 135-93-44; e-mail: ).

 

Область научных интересов:

Макроциклические соединения, синтез, структура, координационные соединения, кинетика, механизм образования, электрохимия, мессбауэровские спектры, топологические лекарства;

 

Основные публикации:

1. Y.Z. Voloshin, N.A. Kostromina, R. Krämer, Clathrochelates: synthesis, structure and properties. Elsevier, Amsterdam, 2002.

2. Voloshin Y,Z., Varzatskii O.A., Kron T.E., Belsky V.K., Zavodnik V.E., Strizhakova N.G., Palchik A.V., Triribbed-Functionalized Clathrochelate Iron(II) Dioximates as a New and Promising Tool To Obtain Polynucleating and Polynuclear Compounds with Improved Properties. Inorg. Chem., 2000, 39, 1907.

3. Voloshin Y.Z., Varzatskii O.A., Kron T.E., Belsky V.K., Zavodnik V.E., Strizhakova N.G., Nadtochenko V.A., Smirnov V.A., Encapsulation of ruthenium(II) with macrobicyclic dioxime-functionalized ligands: on the way to new types of DNA-cleaving agents and probes. Dalton Trans.,  2002, 1203.

4. Voloshin Y.Z., Zavodnik V.E., Varzatskii O.A., Belsky V.K., Palchik A.V., Strizhakova N.G., Antipin M.Y., Clathrochelate monoribbed-functionalized iron(II) α-dioximates: synthetic pathways and structural and electrochemical features. Dalton Trans., 2002, 1193.

5. Y.Z. Voloshin, O.A. Varzatskii, A.V. Palchik, N.G. Strizhakova, I.I. Vorontsov, M.Y. Antipin, D.I. Kochubey, B.N. Novgorodov, First trigonal-antiprismatic tris-dichloroglyoximate iron(II) clathrochelate and its reactivity in nucleophilic substitution reactions, New J.Chem., 2003, 27, 1148.

6. Y.Z. Voloshin, O.A. Varzatskii, M.Y. Antipin, S.V. Korobko, V.Y. Chernii, S.V. Volkov, V.I. Pehn’o, Z.A. Starikova, Ditopic macropolycyclic complexes: synthesis of hybrid phthalocyaninoclathrochelates, Inorg. Chem., 2005, 44, 822.

7. Y.Z. Voloshin, O.A. Varzatskii, I.I. Vorontsov, M.Y. Antipin, Tuning a metal's oxidation state: the potential of clathrochelate systems. Angew.Chem., Int.Ed., 2005, 44, 3400.

8. S.Y. Erdyakov, Y.Z. Voloshin, I.G. Makarenko, E.G. Lebed, T.V. Potapova, A.V. Ignatenko, A.V. Vologzhanina, M.E. Gurskii, Y.N. Bubnov, New o-carboranyl-containing capping agents for d-metal tris-dioximates and first bis-C-carboranylboron-capped iron(II) clathrochelates: Synthesis and X-ray structure, Inorg.Chem.Comm., 2009, 12, 135.

9. Y.Z. Voloshin, O.A. Varzatskii, A.S. Belov, Z.A. Starikova, K.Y. Suponitsky, V.V. Novikov, Y.N. Bubnov, Interaction of dichloride iron(II) clathrochelate with dimercaptomaleodinitrile: synthesis of the precursor of monoribbed-functionalized phthalocyaninoclathrochelates and the unexpected formation of a new thiophene-containing heterocyclic system in the ribbed chelate fragment of the clathrochelate framework, Inorg. Chem., 2008, 47, 2155.

10. Y.Z. Voloshin, O.A. Varzatskii, D.I Kochubey, I.I. Vorontsov, Y.N. Bubnov, Synthesis and structure of monoribbed-functionalized disulfide iron(II) clathrochelates and their coordination as the ligands toward platinum(II) and platinum(IV) ions, Inorg.Chim.Acta, 362, 2009, 149

11. Y.Z. Voloshin, A.S. Belov, O.A. Varzatskii, A.V. Vologzhanina, S. Viswanathan, J. Radecki, Y.N. Bubnov, Synthesis, structure and electron-mediator properties of the mono- and difunctionalized macrobicyclic iron(II) tris-dioximates with thiol terminated ribbed spacer substituents, Inorg. Chim. Acta, 362, 2009, 2982.

12. S. Viswanathan, Y.Z. Voloshin, H. Radecka, J. Radecki, Single molecular switch based on thiol tethered iron(II)clathrochelate on gold, Electrochim. Acta, 54, 2009, 5431.

13. О.А. Varzatskii, Y.Z. Voloshin, S.V. Korobko, S.V. Shulga, R.Krämer, A.S. Belov, A.V. Vologzhanina, Y.N. Bubnov, On a way to new types of the polyfunctional and polytopic systems based on cage metal complexes: cadmium-promoted nucleophilic substitution with low-active nucleophilic agents, Polyhedron, 28, 2009, 3431.

14. Y.Z. Voloshin, O.A. Varzatskii, A.S. Belov, A.V. Vologzhanina, Z.A. Starikova, A.V. Dolganov, V.V. Novikov, Synthesis, X-ray structures and properties of the first tris-dioximate cobalt clathrochelates with nonequivalent chelate ribbed fragments, Inorg. Chim. Acta, 362, 2009, 5144.

15. Y.Z. Voloshin, O.A. Varzatskii, A.S. Belov, Z.A. Starikova, N.G. Strizhakova, A.V. Dolganov, D.I. Kochubey, Y.N. Bubnov, Synthesis, X-ray structure and redox properties of the macrobicyclic iron(II) N₂- and S₂-containing vic-dioximates, Inorg. Chim. Acta, 363, 2010, 134.

16. Y.Z. Voloshin, I.G. Makarenko, S.Y. Erdyakov, S.V. Svidlov, A.V. Vologzhanina, E.G. Lebed, A.V. Ignatenko, M.E. Gurskii, Y.N. Bubnov, Template synthesis, structure and spectra of the semiclathrochelate and clathrochelate 1,4‑pentadienylboron-capped iron(II) oximehydrazonates, Inorg. Chim. Acta, 2010, 363, 395.

17. Y.Z. Voloshin, O.A. Varzatskii, V.V. Novikov, N.G. Strizhakova, I.I. Vorontsov, A.V. Vologzhanina, K.A. Lyssenko, G.V. Romanenko, M.V. Fedin, V.I. Ovcharenko, Y.N. Bubnov, Tris-dioximate cobalt(I, II, and III) clathrochelates: stabilization of different oxidation and spin states of an encapsulated metal ion by ribbed functionalization, Eur. J. Inorg. Chem., 2010, 5401.

18. Y.Z. Voloshin, A.V. Dolganov, O.A. Varzatskii, Y.N. Bubnov, Efficient electrocatalytic hydrogen production from the H⁺ ions using the specially designed boron-capped cobalt clathrochelates, Chem. Commun., 2011, 47, 7737–7739

19. Y.Z. Voloshin, I.G. Belaya (Makarenko), A.S. Belov, V.E. Platonov, A.M. Maksimov, A.V. Vologzhanina, Z.A. Starikova, A.V. Dolganov, V.V. Novikov, Y.N. Bubnov, Formation of the second superhydrophobic shell around an encapsulated metal ion: synthesis, X-ray structure and electrochemical study of the clathrochelate and bis-clathrochelate iron(II) and cobalt(II, III) dioximates with ribbed perfluoroarylsulfide substituents, Dalton Trans., 2012, 41, 737.

20. Y.Z. Voloshin, A.S. Belov, O.A. Varzatskii, S.V. Shul’ga, P.A. Stuzhin, Z.A. Starikova, E.G. Lebed, Y.N. Bubnov, Synthesis and structure of the first clathrochelate iron(II) tris-dioximates with inherent nitrile substituent(s) and new dehalogenation – reduction reaction at a quasi-aromatic macrobicyclic framework, Dalton Trans., 2012, 41, 921.

21. Y.Z. Voloshin, A.S. Belov, A.V. Vologzhanina, G.G. Aleksandrov, A.V. Dolganov, V.V. Novikov, O.A. Varzatskii, Y.N. Bubnov, Synthesis, structure, electrochemical properties and immobilization on a gold surface of the monoribbed-functionalized tris-dioximate cobalt(II) clathrochelates and an electrocatalytic hydrogen production from H⁺ ions, Dalton Trans., DOI: 10.1039/c2dt12513g.